Evaluation of the effect of fenhexamid and mepanipyrim in the volatile composition of Tempranillo and Graciano wines

Food Research International

Volume 71, May 2015, Pages 108–117

doi:10.1016/j.foodres.2015.02.025

Grapes from Vitis vinifera var. Tempranillo and Graciano of La Rioja (North Central Spain) were vinified after addition of two fungicides (mepanipyrim and fenhexamid) at concentrations corresponding to their MRLs. These fungicides are commonly used in the vine growing to control botrytis disease. The fungicide effect throughout winemaking on the volatile composition and aroma profile of the final wines was evaluated, together with the level of fungicide residues in the final wines that were found to be safe for consumers. Concentrations of C13-norisoprenoids in Graciano wines obtained after the addition of both active substances showed the greatest variations with respect to control wine; whereas the concentration of volatile compounds in Tempranillo wines were seemingly unaffected by the presence of fungicide residues. On the other hand, the aroma profile of monovarietal red wines was evaluated by using odorant series which included volatile compounds with similar odour descriptors. In this sense, supplementation with the antifungals seemed to increase the OAV for the ripe fruit series with respect to the control wines in Graciano wines.

Wine Aroma Compounds in Grapes: A Critical Review

Critical Reviews in Food Science and Nutrition, 2015, 55(2), 202-218

Volatile organic compounds are vital to wine quality, determining their aroma and varietal characteristics. Which are present, and in what quantity, depends on the cultivar, the situation and soil of the vineyard, weather, cultivation methods, and wine-making practices. Here, we review the literature on the development of wine aroma compounds in grapes, and how it is affected by the above-named factors. Increasing understanding of these processes at the molecular level will aid vine growers in the optimal selection of harvest dates and other decisions favoring the consistent production of balanced, flavorful berries. 

The measure and control of effects of botryticides on phenolic profile and color quality of red wines

Food Control 2015, 50, 942-948

The effect of the residues of two fungicides (mepanipyrim and fenhexamid) on the color and phenolic profile of Tempranillo and Graciano red wines has been studied. To evaluate possible modifications in color and phenolic composition of wines, control wines (not treated) and wines elaborated with spiked musts were analyzed. Thereby, changes in the color parameters of CIELab space were observed in the wines treated with mepanipyrim and also in Tempranillo wines treated with fenhexamid. In general, the anti-fungal substances had different effects depending on the cultivar and on the phenolic compound analyzed; being monomeric anthocyanins and flavan-3-ol monomers the compounds more affected by the presence of these fungicides.